What is an azeotrope and why does it limit ethanol purity, even with fractional distillation?

Answers

Answer 1
An azeotrope is a mixture of two or more liquids whose proportions remain the same when vaporized. Because of this, fractional distillation is unable to purify ethanol.
Answer 2

Final answer:

An azeotrope is a mixture that retains the same composition in both liquid and vapor states when boiled. This property limits the purity of ethanol to about 95.6% through fractional distillation because the ethanol-water mixture's vapor composition becomes identical to the liquid. To surpass this azeotropic point and obtain higher purity ethanol, specialized techniques must be used.

Explanation:

An azeotrope is a mixture of two or more liquids that retains the same composition in the liquid and vapor states because it boils at a constant temperature. This occurs because the vapor has the same composition as the liquid mixture due to the specific intermolecular interactions between the different components. A common example is the azeotropic mixture of approximately 95.6% ethanol and 4.4% water by mass, which has a boiling point of 78.1 °C.

When attempting to obtain pure ethanol by fractional distillation, the presence of an azeotrope poses a limitation. Since the vapor generated from the azeotropic mixture has the same percentage composition as the liquid, the usual effectiveness of fractional distillation in separating substances based on different boiling points is thwarted. Therefore, achieving ethanol purity higher than 95.6% through conventional distillation is not possible due to the formation of this azeotrope with water.

Some other methods, like the addition of a third component to break the azeotrope or the use of molecular sieves for dehydration, are necessary to produce ethanol with higher purity. In the context of ethanol production, the presence of azeotropes is why standard distillation techniques cannot yield 100% pure ethanol, and additional treatments are needed to reach such high purity levels.


Related Questions

How many covalent bonds does nitrogen form if each of its unpaired electrons participate in one bond?

Answers

Nitrogen has 7 electrons which are configured as (2, 5).
This means that hydrogen needs three electrons in order to saturate its outermost energy level and become stable.

Based on this, nitrogen can form 3 covalent bonds where it shares with one electron in each of the three.

[tex]\boxed{{\text{3}}\;{\text{covalent bonds}}}[/tex] are formed by nitrogen if each of its unpaired electrons participates in one bond.

Further Explanation:

The bond that is formed by the mutual sharing of electrons between the bonded atoms is called a covalent bond. It is also known as a molecular bond. Covalent compounds are those compounds which are formed by the electron sharing between two or more non-metals.

The octet rule is the rule in accordance to which the elements have the tendency to bond with other elements and acquire eight electrons in their valence shells. This results in achieving a stable noble gas configuration.

For example, the formation of [tex]{\text{NaCl}}[/tex] occurs according to the octet rule. The electronic configuration of sodium is [tex]{\mathbf{1}}{{\mathbf{s}}^{\mathbf{2}}}{\mathbf{2}}{{\mathbf{s}}^{\mathbf{2}}}{\mathbf{2}}{{\mathbf{p}}^{\mathbf{6}}}{\mathbf{3}}{{\mathbf{s}}^{\mathbf{1}}}[/tex] while that of chlorine is [tex]{\mathbf{1}}{{\mathbf{s}}^{\mathbf{2}}}{\mathbf{2}}{{\mathbf{s}}^{\mathbf{2}}}{\mathbf{2}}{{\mathbf{p}}^{\mathbf{6}}}{\mathbf{3}}{{\mathbf{s}}^{\mathbf{2}}}{\mathbf{3}}{{\mathbf{p}}^{\mathbf{5}}}[/tex] .

Chlorine is one electron short of the stable noble gas configuration and sodium can achieve stable configuration by losing an electron. So sodium loses an electron and forms cation and chlorine gains that electron to complete its octet.

In case of nitrogen:

The atomic number of nitrogen is 7. Its ground state electronic configuration is [tex]{\mathbf{1}}{{\mathbf{s}}^{\mathbf{2}}}{\mathbf{2}}{{\mathbf{s}}^{\mathbf{2}}}{\mathbf{2}}{{\mathbf{p}}^{\mathbf{3}}}[/tex] . The partial orbital diagram is the diagrammatic representation of the distribution of electrons in the valence shell only. In case of nitrogen, the valence shell is 2s and 2p.(Refer to the attached image).

Nitrogen atom consists of five electrons in its valence shell. Out of these five electrons, two are paired and present in 2s while three remain unpaired in 2p. If all three unpaired electrons are to be used, it will accept three electrons from the neighboring atoms to make three covalent bonds. The octet of nitrogen is completed with the formation of three covalent bonds with neighboring atoms.

Learn more:

1. Identification of ionic bonding: https://brainly.com/question/1603987

2. Chemical bonds in NaCl: https://brainly.com/question/5008811

Answer details:

Grade: High School

Subject: Chemistry

Chapter: Ionic and covalent compounds

Keywords: covalent bonds, nitrogen, unpaired electrons, bond, 3, paired electrons, covalent compounds, molecular bond, covalent bond, mutual sharing of electrons, five electrons, partial orbital diagram, distribution of electrons.

Consider the chemical reaction in equilibrium.

H2 + I2 + heat mc006-1.jpg 2HI

What will happen to the chemical equilibrium if the temperature of the system is increased?
The direction of the chemical equilibrium will shift to the right, favoring the forward reaction.
The chemical equilibrium will not be affected by an increase in temperature.
The direction of the chemical equilibrium will shift to the left, favoring the reverse reaction.
The chemical equilibrium will be lost permanently with a change of temperature.

Answers

The correct option is A.
The chemical equation given above is an endothermic reaction. An endothermic reaction is a type of reaction which absorb heat from the environment. An endothermic reaction needs heat to occur, therefore, increasing the temperature of such a reaction will favor the formation of more product and the equilibrium of the reaction will shift [forward] to the right, which is the product side.
"A. The direction of the chemical equilibrium will shift to the right, favoring the forward reaction. " is the correct answer

The maximum growth yield coefficient for bacillus subtilis growing on methanol is 0.4 gx/gs. the heat of combustion of cells is 21 kj/gx and for substrate it is 7.3 kcal/g. determine the metabolic heat generated by the cells per unit mass of methanol consumption.

Answers

To solve this problem, we simply have to find for the value which corresponds to a unit of unit energy per unit mass substrate. That is:

 

metabolic heat = 21 kJ / g X * (0.4 g X / g S)

metabolic heat = 8.4 kJ / g S

Predict the products when cyclohexanol is dehydrated.

Answers

When cyclohexanol is dehydrated using various means it creates a new hydrocarbon. This new hydrocarbon is called cyclohexene. Cyclohexene is a liquid which has no color, yet has a very strong smell to it. It is used in common industrial processes, but is also considered somewhat unstable due to it's tendency to form peroxides when exposed to light.

Dehydration reactions are those chemical processes that remove a water molecule from the reactant molecule. Here the product formed when cyclohexanol is dehydrated is Cyclohexene.

These processes are known as synthesis reactions because they produce new compounds with complex structures.

Cyclohexanol produces a new hydrocarbon when it is dehydrated in various ways. Cyclohexene is the name of this novel hydrocarbon. Although cyclohexene is a colorless liquid, it possesses a potent odor.

cyclohexene is employed in typical industrial operations, but because of its propensity to produce peroxides when exposed to light, it is also regarded as being relatively unstable.

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is there any evidence that methanol forms ions either in the pure state or when dissolved in water?

Answers

According to research, the answer is no. Although alcohol is dissolves in water solution but dissociation of methyl alcohol in into ions is barely not possible. Thus, methanol is considered as a non-electrolyte.
Final answer:

Methanol is soluble in water due to its polarity and the formation of hydrogen bonds. It does not form ions in its pure state or when dissolved in water.

Explanation:

Water is polar, which means that substances that are polar or ionic will dissolve in it. Methanol, which has the OH group, is a polar molecule. Therefore, it is soluble in water. Both water and methanol are liquid and can mix together well, so the term 'miscible' can be used to describe their solubility.

In addition to its solubility, hydrogen bonding occurs between methanol and water molecules. This phenomenon accounts for the solubility of methanol in water. Methanol forms hydrogen bonds with water through the interaction between the OH group of methanol and water molecules.

Methanol does not form ions either in its pure state or when dissolved in water. It remains in its molecular form in both cases.

For what reason might one guess that the compound (clo4)2so4 is never observed?

Answers

You didn't attached the choices in this question but the answer will be Sulfate and perchlorate both have negative oxidation states.
The reason might one guess that the compound (clo4)2so4 is never observed because Sulfate and perchlorate both have negative oxidation states.

Which is stronger - the attractive forces between water molecules and chromium and chloride ions, or the combined ionic bond strength of crcl2 and intermolecular forces between water molecules? explain?

Answers

Out of the two, the forces between water molecules and chromium and chloride ions is greater. This is proven by the fact that chromium chloride is slightly soluble in water, about 565 grams per liter.
In order for a substance to be soluble, the attraction of the ions to the water molecules must exceed the attraction between its own molecules and the water molecules.
Final answer:

Intramolecular forces such as the ionic bond strength in a CrCl2 molecule tend to be stronger than the intermolecular forces, which include the attractive forces between water molecules and chromium chloride ions.

Explanation:

The attractive forces between water molecules and chromium (Cr) and chloride (Cl) ions, or the ionic bond strength in a CrCl2 molecule, can be compared by analyzing intermolecular forces and intramolecular forces. Intramolecular forces are those within the molecule that keep the molecule together, like the ionic bonds in a CrCl2 molecule. These forces are typically much stronger compared to intermolecular forces. Intermolecular forces, on the other hand, are the attractions between molecules, such as the attractive forces between water and Cr and Cl ions. Using water as an example, it has strong intermolecular forces of hydrogen bonding leading to high surface tension. However, the energy required to overcome these forces (around 17 kilojoules for one mole of water) is significantly less than the energy required to break the covalent bonds in the water molecule itself (about 430 kilojoules). Therefore, intramolecular forces like the ionic bond strength of CrCl2 are generally stronger than intermolecular forces between water molecules and Cr and Cl ions.

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Which location on Earth is the crust the thickest?

Answers

I dont know sorry i wish i could help you

The continental crust, or the crust that lies beneath the continents, usually ranges from around 30 to 45 kilometers thick. These thicknesses are found on most continents and are dependent on height above sea level and mountainous regions. Although there are rare areas that exceed 70 kilometers thick, according to the United States Geological Survey, or USGS, less than 10 percent of the total area of the Earth's crust exceeds 50 kilometers thick.

Thicknesses below 30 kilometers are typically only found under the ocean and are called oceanic crust. The thinnest sections of the crust are only approximately five kilometers thick, which is a small fraction of the thickness of the thickest parts of the continental crust. The thickness of oceanic crust is difficult to estimate by looking only at proximity to continents or latitude since the crust varies greatly from coast to coast and everywhere in between. For example, along the eastern coast of the United States, the oceanic crust ranges from 10 to 30 kilometers thick, according to the USGS.

A sample of lsd (d-lysergic acid diethylamide, c24h30n3o) is added to some table salt (sodium chloride) to form a mixture. given that a 1.00-g sample of the mixture undergoes combustion to produce 1.20 g of co2, what is the mass percent of lsd in the mixture?

Answers

1) All the CO2 comes from the C24 H30 N3 O

2) To balance C from CO2 with C from C24, the ratio of cC24 H30 N3 O to CO2 is 24 / 1

3) Convert 1.20 g of CO2 to number of moles

number of moles = mass in grams / molar mass

mass = 1.20 g

molar mass = 12.01 g/mol + 32.00 g/mol = 44.01 g/mol

number of moles = 1.2 g / 44.01 g/mol = 0.0273 mol

4) proportion

1 mol C24 H30 N3 O / 24 mol CO2 = x / 0.0273 mol CO2

=> x = 0.0273 mol CO2 * 1 mol C24H30N3O / 24 mol CO2 = 0.00114 mol C24H30N3O

5) Convert 0.00114 mol C24H30N3O to grams

molar mass = 376.5 g/mol

mass = 0.00114 mol * 376.5 g/mol = 0.429 g

6) mass percent in the mixture

mass percent = (mass of lsd / mass of mixture) * 100 = (0.429g / 1.0g) * 100 = 42.9%

Answer: 42.9%


mixtures cannot be separated by physical means how is a pure substance different from a mixture how is a pure substance different from a mixture the pure substance different from a mixture

Answers

A pure substance is different from a mixture because a pure substance is only made of one substance a mixture is made up of all sorts of different substances. Hope this helps you!

Answer:

the mixture is made of one substance

Explanation:

I did the quiz

Which statements are true of all scientific endeavors? Check all that apply.


All scientific endeavors are time consuming.

All scientific endeavors are expensive.

All scientific endeavors are supported by evidence.

All scientific endeavors are a systemic process.

All scientific endeavors involve observation.

All scientific endeavors involve experimentation.

All scientific endeavors involve the collection of information.

Answers

Scientific endeavors is basically all the things that would contribute to the process of achieving a certain scientific knowledge, from the initial observation, up to the point until we can hold that certain thing as acknowledged truth.  So,

All scientific endeavors are supported by evidence.
All scientific endeavors are a systemic process.
All scientific endeavors involve observation.
All scientific endeavors involve experimentation.
All scientific endeavors involve the collection of information.

Answer:

i think its C

Explanation:

Peroxisomal enzymes __________. 1) produce hydrogen peroxide 2) break down hydrogen peroxide 3) include catalase

Answers

From the word itself, peroxisomal enzymes has to do with hydrogen peroxide. So, the answer could only be either choice (1) or (2). The correct answer would be choice (2). These enzymes are useful in breaking down hydrogen peroxide to produce water.

A chemist requires 0.811 mol Na2CO3 for a reaction. How many grams does this correspond to?

Answers

mol=mass in g÷Mr
Mass=mol×Mr
=0.811×(add up mass of all elements)
=0.811×(16×3+23×2+12)
=85.966g

List the steps in the process of calculating average atomic mass given data about the isotopes of an element

Answers

1) Find out the relative abundance of each isotope. ex. Carbon 13 has around 0.01% while Carbon-12 has around 99.98%
2) Multiply each isotope by its abundance. Ex: 13(0.01) and 12(99.98)
3) add the abundances Ex. 13(0.01) + 12(99.98) = (should be around 12.01, but i just plugged in random percentages. I hope you get the point)

Tip: In a mass pectrometry graph, if it asks you for an average atomic mass of an element, 90% of the time it's going to be in the periodic table, as the mass of the element in the period table IS the average atomic mass. 

Five moles of an ideal gas expands isothermally at 300 k from an initial volume of 100 l to a final volume of 500 l. calculate

Answers

The question is incomplete. But this is a typical thermodynamic problem. Looking at the given data and knowing that it is an isothermal process, the most probable question would be, the final pressure of the system. The solution is as follows:

For state 1,
PV=nRT
P₁(100 L)(1 m³/1,000 L) = (5 mol)(8.314 m³Pa/molK)(300 K)
P₁ = 124,710 Pa

For isothermal process:
P₁V₁ = P₂V₂
(124,710 Pa)(100 L)= P₂(500 L)
Solving for P₂,
P₂ = 24,942 Pa

What was the weight percent of water in the hydrate before heating?
Put answer in one decimal place.
weight of water 0.349
weight of hydrate 2.107

Answers

Data:

weight of water before heating = 0.349

weight of hydrate before heateing = 2.107

Formula:

Weight percent of water = [ (weight of water) / (weight of the hydrate) ] * 100

Solution:

Weight percent of water = [ 0.349 / 2.107] * 100 ≈ 16.6 %

Answer: 16.6%
Final answer:

The weight percent of water in the hydrate before heating is 16.58%.

Explanation:

To find the weight percent of water in the hydrate before heating, we need to calculate the percent by mass of water. This can be done by dividing the mass of water in 1 mole of the hydrate by the molar mass of the hydrate, and then multiplying by 100%. The formula for weight percent is:

Weight percent = (mass of water / mass of hydrate) x 100%

Given that the weight of water is 0.349 grams and the weight of the hydrate is 2.107 grams, we can substitute these values into the formula:

Weight percent = (0.349 g / 2.107 g) x 100% = 16.58%

Hence, The weight percent of water in the hydrate before heating is 16.58%.

What fraction of carbon 14 remains in an animal frozen in a glacier 18000 years ago?

Answers

The formula we can use here is:

A = Ao e^(-kt)

where A is the amount remaining, Ao is the initial amount, A/Ao is the fraction we need, k is the rate constant and t is number of years passed

 

First we need to find k using the half life formula:

t1/2 = ln 2 / k

The half life of C 14 is t1/2 = 5730 years

therefore k is:

k = ln 2 / 5730 years

k = 1.21 x 10^-4 years-1

 

Going back:

A/Ao = e^(-kt)

A/Ao = e^(-1.21 x 10^-4 years-1 * 18000 years)

A/Ao = 0.1133

 

So only about 11.33% remains.

Which statement describes how NO2- reacts in this equilibrium H2SO3(aq) + NO2-(aq) HSO3-(aq) + HNO2(aq)

Answers

the second statement

23492u undergoes alpha decay. what is the atomic number of the resulting element.

Answers

Alpha decay involves the loss of an alpha particle, aka a helium nucleus. This results in the mass number of the original element decreasing by 4 and the atomic number decreasing by 2. Assuming 23942u is uranium (92), the resulting element's atomic number is 90, making it thorium.

Is deionized water a homogeneous mixture?

Answers

Deionized water is regarded as pure water, which is a compund, not a mixture. A mixture requires that there are 2 different pure componds combined, with a homogeneous mixture requiring that the apperance is consistent and uniform. Because it is a compound, deionized water cannot be a homogenous mixture. instead, an example of a homogeneous mixture would be salt water

The process of __________ turns water vapor to liquid.

Answers

I belive this is called condensation.
hope this helps!

When dissolved in water, a(n) ______ donates h+ ions and a(n) ______ accepts h+ ions?

Answers

The correct answer is acid ,base

The enzyme α-amylase increases the rate at which starch is broken down into smaller oligosaccharides. it does this by
a. decreasing the equilibrium constant of the reaction.
b. increasing the change in free energy of the reaction.
c. decreasing the change in free energy of the reaction.
d. increasing the change in entropy of the reaction.
e. lowering the activation energy of the reaction.

Answers

by lowering activation energy
E is your answer

The enzyme α-amylase increases the rate of starch breakdown by lowering the activation energy of the reaction, which is option (e). Enzymes act as catalysts in metabolic processes, and their activity can be influenced by environmental factors such as pH and temperature.

The enzyme α-amylase increases the rate at which starch is broken down into smaller oligosaccharides by lowering the activation energy of the reaction. This process does not require altering the equilibrium constant or the change in free energy; rather, it involves facilitating the reaction so that the energy barrier is lower, allowing the reactants to convert into products more easily. In the options provided, the correct answer to how α-amylase increases the rate of the reaction is (e) lowering the activation energy of the reaction.

An enzyme's role is to act as a catalyst, speeding up chemical reactions without being consumed or permanently changed by the reaction. Enzymes are crucial for metabolic processes, such as the hydrolysis of starch into sugars like glucose and maltose, which are used by cells as a source of energy and carbon. Parameters that can influence the activity of α-amylase include pH and temperature, which if not optimal, can reduce the rate of the reaction.

the formula for magnesium chloride is MgC12. how many magnesium atoms are there in one molecule?

Answers

There is one in MgCl2. Since there is no subscript beside Mg, there is only one atom.
There is only one magnesium atom in one molecule.for the clorine i would say only two chlorine atoms in one molecule. i hope this has helped you.

Alkenes: draw the product of 1-chloro-2-ethylcyclohexene with hydrogen gas and a platinum catalyst

Answers

Reacting 1-chloro-2-ethylcyclohexene with hydrogen gas using a platinum catalyst would give a product of 1-chloro-2-ethylcyclohexane. 

Hydrogen gas is a reducing agent, which in this reaction, simply mean that the alkene double bond in the cyclohexene will disappear because one of the two bonds forming the double bond (in the alkene) will be connected to a hydrogen atom. The platinum catalyst is necessary to allow the reaction to proceed at a much lower (activation) energy than would have been required. 

when an element exists in nature by itself, it must have a charge of

Answers

Final answer:

An element existing in nature by itself, such as a neutral atom, will have an overall charge of zero due to the balanced number of protons and electrons.

Explanation:

When an element exists in nature by itself, it is in the form of a neutral atom, which means it must have an overall charge of zero. This neutrality is achieved because the atom has an equal number of protons and electrons, and since protons and electrons carry equal but opposite charges, their charges cancel each other out. The proton carries a positive charge, and the electron carries a negative charge, both with a magnitude of 1.60×10-19 coulombs (C). Neutral atoms may form molecules by sharing electrons via covalent bonds but still retain no net charge unless they lose or gain electrons to become ions. Therefore, in its most stable form, an element on its own will exhibit a charge of zero.

The ka of acetic acid ch3co2h is 1.8 x10-5. what is the ph

Answers

You must know the concentration of the acetic acid. Suppose the concentration is 0.1 M. The solution is as follows:

            CH₃COOH → CH₃COO⁻ + H⁺
 I                  0.1               0              0
C                 -x                +x            +x
E              0.1 - x             x               x

Ka = (x)(x)/(0.1 - x)
1.8×10⁻⁵ = x²/(0.1 - x)
Solving for x,
x = 1.333×10⁻³ = H⁺

pH = -log[H⁺] = -log(1.333×10⁻³)
pH = 2.88

If you performed this experiment using mgcl2 as the solute would the molar concentration of mgcl2 that is isotonic to the potato be higher, the same or lower than the molar concentration of nacl that is isotonic to the potato? explain.

Answers

The answer to this question would be: lower molar concentration

Osmotic pressure is influenced by the number of ions and the concentration of the molecule in the solution. In NaCl, the molecule will split into 1 Na+ ion and 1 Cl- ion which results in 2 ions per compound. In MgCl2, the compound will split into 1 Mg2+ ion and 2 Cl- ion which results in 3 ions. Therefore, the osmotic pressure of MgCl2 will be 3/2 times of NaCl.
MgCl2 will need less concentration to achieve same osmotic pressure as NaCl. If the MgCl2 solution is isotonic with NaCl, the concentration of MgCl2 would be lower than NaCl

The molar concentration of MgCl₂ that is isotonic to the potato would be lower than that of NaCl. This is because MgCl₂ produces three ions in solution compared to the two ions from NaCl, affecting their respective osmolarities.

The molar concentration of MgCl₂ that is isotonic to the potato would be lower than the molar concentration of NaCl that is isotonic to the potato. This difference is because MgCl₂ dissociates into three ions (one Mg2⁺ and two Cl⁻) in solution, whereas NaCl dissociates into only two ions (one Na⁺ and one Cl⁻).

Since the isotonic condition depends on the total number of particles (osmolarity) in the solution, a smaller molar concentration of MgCl₂ can achieve the same osmolarity as a higher molar concentration of NaCl.

So, the dissociation of solutes affects their molar concentrations required to be isotonic. MgCl₂ dissociates into more particles than NaCl, leading to a lower molar concentration of MgCl₂ needed to match the osmolarity for isotonicity with a potato compared to NaCl.

For the complete redox reactions given here write the half-reactions and identify

Answers

I don't know what your asking so Identify means your self

Shade all the elements for which the neutral atom has a valence electron configuration of ns2np6 , where n stands for an integer.

Answers

The elements for which the neutral atom has a valence electron configuration of .

[tex]ns^2np^6[/tex]

are those whose valence electron shell has 2 + 6 = 8 electrons.

Those are the noble gases, except helium (He).

Here is the list of the noble gases and the configuration of their valence electron configuration:

He:     [tex]1s^2[/tex]

Ne      [tex]2s^22p^6[/tex]

Ar       [tex]3s^23p^6[/tex]

Kr       [tex]4s^24p^6[/tex]

Xe       [tex]5s^25p^6[/tex]

Rn      [tex]6s^26p^6[/tex]

Answer: Ne, Ar, Kr, Xe and Rn
Final answer:

Elements with a valence electron configuration of ns2np6 include oxygen, sulfur, and chlorine.

Explanation:

The valence electron configuration ns2np6 corresponds to the noble gas electron configuration of elements in Group 18 (the noble gases) of the periodic table, such as neon (atomic number 10) with the electron configuration of 1s²2s²2p⁶. The elements with ns2np6 valence electron configuration include oxygen (atomic number 8) with the electron configuration of 1s²2s²2p⁴, sulfur (atomic number 16) with the electron configuration of 1s²2s²2p⁶3s²3p⁴, and chlorine (atomic number 17) with the electron configuration of 1s²2s²2p⁶3s²3p⁵.

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