ligand field diagram for octahedral complex explain briefly

Answers

Answer 1

The ligand field diagram for octahedral complex is explained here.

In a free metal ion, all the five d-orbitals are degenerate (i.e, having equal energies). But according to crystal field theory, under the influence of ligand field, degenracy of d-orbital is destroyed and they split into two or more energy levels. The difference in energy between two sets of d-orbitals is called Crystal Field Splitting Energy (CFSE). The extent of splitting depends upon the strength of ligand. A strong ligand causes greater splitting whereas weak ligand causes smaller splitting.

In octahedral complex, under the influence of ligand field, degenerate five d-orbitals  split into two sets of orbitals -one is [tex]t_{2g}[/tex] and another one is [tex]e_{g}[/tex]. [tex]t_{2g}[/tex] orbital consists of [tex]d_{xy} , d_{xz} , d_{yz}[/tex] and [tex]e_{g}[/tex] orbital consists of [tex]d_{x^{2}-y^{2}  }  and   d_{z^{2} }[/tex] orbitals.

The crystal field splitting diagram for octahedral complex is attached here.

In the diagram, Δo is crystal field splitting energy (CFSE).

Ligand Field Diagram For Octahedral Complex Explain Briefly

Related Questions

When Calcium (Ca) is mixed with Hydrochloric acid (HCI), a single-displacement reaction occurs. What will be the product or products?

a) CaCI2
b) CaCI2+H2
c) Ca+HCI
d) CI and H

Answers

The correct answer is b. In a single-displacement reaction one element replaces another one, and because of BrINClHOF we know that hydrogen must have a 2 with it when it's by itself. Since calcium is +2 and chlorine is -1, you have to cross the charges. So it would be CaCl2.

Answer: The correct answer is Option b.

Explanation:

Single displacement reaction is defined as the reaction in which more reactive element displaces a less reactive element from its chemical reaction.

The reactivity of metal is determined by a series known as reactivity series. The metals lying above in the series are more reactive than the metals which lie below in the series.

When calcium metal reacts with hydrochloric acid, it leads to the formation of a salt known as calcium chloride and also releases hydrogen gas.

The chemical equation for the above reaction follows:

[tex]Ca(s)+2HCl(aq.)\rightarrow CaCl_2(s)+H_2(g)[/tex]

Hence, the correct answer is Option b.

calculate the hydroxide ion concentration [OH-] for a solution with a pH of 6.10

Answers

There are different formula you need to keep in mind when solving for [OH-]

Given that pH = 6.10

pH + pOH = 14

6.10 + pOH = 14

pOH = 7.9

[OH-] = 10^(-pOH)

[OH-] = 10^(-7.9)

[OH-] = 0.000000013

[OH-] = 1.3 x 10^-8


Answer: [OH-] = 1.3 x 10^-8

The hydroxide ion concentration in an aqueous solution is equal to 10⁻⁸M.

What is the pOH?

pOH can be determined by taking the negative logarithm of the hydroxide ions concentration in the given aqueous solution.

Mathematically, pOH can be expressed in the form of hydroxide ion concentration as follows:

pOH = - log  [ OH⁻]                                                

and, [tex]pH + pOH = 14[/tex]                                                        ..............(1)

where [OH⁻] is the hydroxide ions concentration present in an aqueous solution.

Given, the value of pH of the solution containing hydroxide ions:

pH = 6.10

Substitute the value of the pH in equation (1):

pH - log [OH⁻] = 14

6.10 - log [OH⁻] = 14

log [OH⁻] = - 7.9

[OH⁻] = [tex]10 ^{-7.9}[/tex]

[OH⁻] ≈ 10⁻⁸ M

Therefore, the concentration of the hydroxide ions in an aqueous solution is equal to 10⁻⁸ M.

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Which pair of atoms is most likely to be covalently bonded?
1) Na and O
2) K and F
3) Ne and O
4) C and S

Answers

1)Na and O - ion bond
2)K and F - ion bond
3)Ne and O - no bond (as Ne is a noble gas)
And by elimination, your answer is 4)

1 and 2 are a metal - nonmetal pair - that kinda means ionic bond. Na and F are going to lose electrons.

3 [Nonmetals bond to each other covalently! Ne and O are nonmetals. O would need 2e to become stable. Either getting 2e (ionic bond) or sharing 2e (with H, for example). However, Ne is a noble gas, which means it is already doing fine with its 8e on its valence shell and isn't gonna share 2e of its electrons with O. So, despite the fact that they are both nonmetals, they won't form a covalent bond.

Sum up: they are 2 gases haha, and one of them is a noble one. They will never bond to each other covalently

4 - C and S - right answer

As they are both nonmetals (nonmetals bond to each other covalently, none of them is a noble gas, and so on)

why is bronze preferred in making statue

Answers

Bronze metal is harder and more malleable than copper. It is also conducts property of ductility, so it can be easily shaped as a statue.

How does weathering change rock and minerals

Answers

Weathering is the process of breaking large rocks and boulders into much smaller ones. Weathering can be brought about by wind and water mostly. Sometimes even biological forces account for some types of weathering.

Weathering describes the breaking down or dissolving of rocks and minerals on the surface of the Earth. Water, ice, acids, salts, plants, animals, and changes in temperature are all agents of weathering. Once a rock has been broken down, a process called erosion transports the bits of rock and mineral away.

How do you find out how many protons,electrons, and neutrons an atom has?

Answers

so the atomic number is the same as protons, and electrons and to get neutrons by subtracting number of protons from atomic mass.
Final answer:

An atom's atomic number equals the number of protons and in a neutral atom, also, the number of electrons. The mass number equals the total number of protons and neutrons. Subtracting the atomic number from the mass number gives the number of neutrons.

Explanation:

In order to determine the number of protons, neutrons, and electrons an atom has, you need to understand the key terms: atomic number and mass number. The atomic number of an element represents the number of protons in an atom and, in a neutral atom, this also equals the number of electrons. The mass number (or atomic mass) is the total amount of protons and neutrons in an atom. To find out the number of neutrons in an atom, you subtract the atomic number from the mass number. Hence, if the atomic number (Z) represents the number of protons and the mass number (A) represents the number of protons plus neutrons, the formula A - Z = number of neutrons can be used to find the number of neutrons in an atom.

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The more the particles an object has at a given temperature, the more thermal energy it has. True or false

Answers

This is im 90% sure false because if an object is bigger it doesnt mean that its temperature is higher :)

The movement of thermal energy from a warmer object to a cooler object is called. heat ... The more particles an object has at a given temperature

Fullerene is a perfect sphere with the chemical formula c60. From this information, what you can deduce about the structure of fullerenes?

1. It only contains one elements
2. It is a compound of 60elements
3. It is a mixture of 60 atoms
4. It is a mixture of 60 elements

Answers

1. It only contains one element

Answer:

1. It contains only one element.

Step-by-step explanation:

The formula of fullerene is C₆₀.

Fullerene is a compound. One molecule of fullerene contains 60 atoms of one element, carbon.

2. is wrong, because fullerene consists of only one element.

3. and 4. are wrong, because fullerene is a compound.

The muscular system and the nervous system work together by

Answers

Muscles protect the network of nerves that run throughout the body

Answer:

Muscles protect the network of nerves that run throughout the body

Explanation:

I thank to

Neptune is 30.6 au from the sun. How long is the year for neptune?

Answers

a) P^2=a^3=30.6^3=28650

b) P=28650=169 years

Final answer:

Neptune takes approximately 165 Earth years to complete one orbit around the sun, as it orbits at a distance of 30 AU from the sun.

Explanation:

The orbital period of Neptune, which is the time it takes for Neptune to complete one orbit around the sun, is approximately 165 Earth years. This is because Neptune orbits at an average distance of 30 astronomical units (AU) from the sun. One AU is the average distance between the Earth and the Sun, which is about 1.496×108 km. Given that Neptune is 4.490×109 km away from the Sun, and considering the substantial distance as compared to Earth's orbit, Neptune's year is much longer.

A sulfur atom has a mass number of 31, 16 protons, 15 protons, and 18 electrons. What is the charge of this atom

Answers

Answer:

It should be -2; like hydrogen sulfide H2S

Explanation:

(02.01 LC)
What type of relationship exists between two organisms if both of them benefit from the relationship? (4 points)


Commensalism

Competition

Mutualism

Parasitism

Answers

I think its mutualism

When you push downward on Earth to make a pole vault, does Earth exert an equal source on the pole?

Answers

Yes, Every action has an equal and opposite reaction.

what is a stationary front?
A) A high pressure system equally matched to a low pressure system and not moving
B) High pressure system overtaking a low pressure system
C) Low pressure system overtaking a high pressure system
D) None of the above

Answers

None Of the Above

Is the answer

Hope this helped plz mark


Hi There!

Question - What is a stationary front?

Answer - None of the above.

Why - The reason I say this because in a stationary front its made of low pressure systems so its not A or B. The wind blows the low pressure system which cause precipitation. If its not D then is C.

Hope This Helps :)

Sometimes clothes removed from the dryer cling together. What kinds of charges are on the clothes ?

Answers

The answer is "opposite charges."

Final answer:

When clothes are removed from the dryer and cling together, it is because static electricity is created from the clothes rubbing together in the dryer. This results in an imbalance of electrical charge on the clothes, with some having a net positive charge and others a net negative charge, which makes them attract and stick to each other.

Explanation:

When clothes are removed from the dryer and they cling together, this is due to the presence of static electricity. Static electricity occurs when materials are rubbed together, causing an exchange of electrons. This exchange results in the materials being electrically charged. In the case of your dryer, the process of tumbling and rubbing the clothes together can strip electrons from the clothes and deposit them on other pieces.

This creates an imbalance in charge, leading to some clothes having a net positive charge and others with a net negative charge. The positively charged clothes are attracted to the negatively charged ones, and this attraction causes the clothes to stick together. The force that brings these different charged clothes together is called electrostatic force. If the clothes are damp, the presence of water molecules can suppress the charge, reducing the static cling.

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what will the charge oxidiation state be for boron

Answers

3+

So, compounds of boron contain boron in a positive oxidation state, generally +3. The sum of oxidation numbers of all constituent atoms of a given molecule or ion is equal to zero or the charge of the ion, respectively. ... In most of the stable compounds of boron, its oxidation number is +3

"The charge oxidation state for boron in its compounds is typically +3.

To understand why boron typically has an oxidation state of +3, one must consider the electron configuration of boron and its position in the periodic table. Boron is the first element in group 13 (IIIa) and has an electron configuration of [tex]1s^2 2s^2 2p^1[/tex]. This means it has three electrons in its outermost shell.

In chemical compounds, boron tends to form three covalent bonds with other atoms to fill its outer shell, achieving an octet configuration similar to that of noble gases. By sharing its three valence electrons with other atoms, boron effectively loses three electrons, which corresponds to an oxidation state of +3.

For example, in the compound boron trifluoride (BF3), boron forms three covalent bonds with fluorine atoms. Each fluorine atom has seven electrons in its outer shell and needs one more electron to complete its octet. By sharing one electron with boron, each fluorine atom completes its octet, and boron, by sharing three electrons, also achieves a stable configuration. In this compound, boron has an oxidation state of +3 because it has effectively lost three electrons to the more electronegative fluorine atoms.

Similarly, in other boron compounds like boron trioxide[tex](B_2O_3)[/tex]or boron nitride (BN), boron also exhibits an oxidation state of +3. This is a characteristic feature of boron's chemical behavior and is a direct consequence of its electron configuration and its position in the periodic table.

At what time should we definitely seek shade to avoid sun exposure?
A:Between 6 a.m. and 8 a.m.
B:Between 8 a.m. and 10 a.m.
C:Between 10 a.m. and 4 p.m.
D:Between 4 p.m. and 10 p.m.
Couldn't find Science in the "Pick a subject" box ;-;

Answers

c between 10 and 4.

We should definitely seek shade to sun exposure between 10 A.M. and 4 P.M.

Hope this helped!

How is Earth's surface most likely to change as water freezes and expands on a mountain side over time?

A.) Erosion will cause the ice to crack the rock.
B.) Physical weathering will cause the ice to crack the rock.
C.) Deposition will cause the water to break the rock into sediment.
D.) Chemical weathering will cause the water to dissolve the rock.

Answers

B. Physical weathering will cause the ice to crack the rock.


Answer:

The correct answer is B.

Explanation:

The Earth's surface as water freezes and expands on a mountain slope will cause ice to break the rock. This occurs because the ice occupies a larger volume than the liquid, so it displaces the rock and causes it to break. When the water that accumulates in the rocks freezes, its volume increases in solid-state and exerts a greater pressure, enough to break the rock.

Have a nice day!

How does the gravity of the sun and the moon affect the earths tides

Answers

Long, the ocean tides we experience on earth are caused by the sum of the moon's gravitational gradient and the sun's gravitational gradient. When the sun and the moon are aligned, or nearly aligned, their gravitational gradient fields add together constructively, leading to extra strong tides (high tide is extra high and low tide is extra low). This alignment happens when the moon is a new moon or a full moon, which occurs about every two weeks. The moon takes about a month to orbit the earth, hence strong tides occur about twice a month. In contrast, when the sun and the moon are unaligned, their gravitational gradients tend to cancel out, leading to weak tides (high tide is not very high and low tide is not very low). But even when the sun and moon are perfectly unaligned (they form a 90 degree angle relative to the earth), there are still tides because the moon's gravitational gradient is stronger than the sun's. The sun's gravitational gradient never completely cancels out the moon's. The biweekly strong tides are called "spring tides" even though they occur all year long. The name does not refer to the season "Spring", but to the verb "spring" which means to leap forth, because the strong high tides leap higher up the shore. The biweekly weak tides are called "neap tides".

Final answer:

The Sun and Moon's gravity causes Earth's tides, with the Moon having a greater effect due to its proximity. Spring tides happen when the Earth, Moon, and Sun are aligned, and neap tides occur when the Sun and Moon are at a 90° angle.

Explanation:

The gravity of the Sun and the Moon significantly affects the Earth's tides through a phenomenon known as the tidal effect. Although the gravitational pull of the Sun is nearly 200 times that of the Moon, the tidal effect of the Moon is stronger because of its closer proximity to Earth. The gravitational forces of these celestial bodies cause bulges in Earth's oceans, creating high tides on the sides of Earth closest and farthest from the Moon, and to a lesser extent, from the Sun. This variability in high tides is due to the different positions of the Sun and Moon relative to Earth. The largest tides, known as spring tides, occur when the Earth, Moon, and Sun are aligned, while the smallest tides, neap tides, happen when the Sun and Moon are at 90° angles relative to Earth.

what is the electronegativity in the determination of the ionic or covalent character of a bond

Answers

Polar Covalent is the name used to describe bonds that have both ionic and covalent character because the electrons are shared unequally. The Pauling Scale is used to assign electronegativity to atoms. It ranges from to 4.00 (fluorine).

Final answer:

The electronegativity difference between two atoms in a bond determines the ionic or covalent character of the bond. A greater difference in electronegativity indicates a more polarized electron distribution and larger partial charges of the atoms. Small or zero electronegativity differences indicate nonpolar covalent bonds.

Explanation:

The electronegativity in the determination of the ionic or covalent character of a bond is calculated by finding the difference in electronegativity between the two atoms in the bond. Electronegativity is a measure of the tendency of an atom to attract electrons towards itself in a chemical bond. The greater the difference in electronegativity, the more polarized the electron distribution and the larger the partial charges of the atoms. If the electronegativity difference is very small or zero, the bond is covalent and nonpolar. When the difference is large, the bond is polar covalent or ionic.

According to Kirchhoff’s third law, when light from a blackbody having a continuous spectrum passes through a cool transparent gas, are observed in the continuous spectrum

Answers

When light with a continuous spectrum (emitted by a black body) passes through a cool transparent gas, dark lines are observed in the continuous spectrum.


Answer is dark lines

When light from a black body having a continuous spectrum passes through a cool transparent gas, observed in the continuous spectrum are absorption and emission.

What is a black body?

The black body is an object or material of black color which absorbs the lights of every type of wavelength either it is blue of the lowest wavelength or red of the highest wavelength.

The radiation emitted by a black body is called the radiation of a black body. The stars almost act like a black body. The amount of radiation emitted by the length of each wavelength depends only on the temperature of the object.

Therefore, light from a blackbody having a continuous spectrum passes through a cool transparent gas, observed in the continuous spectrum are absorption and emission.

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A known compound contains two atoms of sulfur into atoms of oxygen write the name and formula of this compound

Answers

S+O2 =SO2 SULFUR DENOTE S  

TWO ATOM OF OXYGEN DENOTE O2

Match the bond to its formula

Answers

1. ionic NaCl

2. covalent CO2

3.metallic ZnCu

The type of decay associated with the emission of a photon is

Answers

Gamma Decay in the nucleus is similar to Photon Decay in atoms. When a electron charges energy levels in the atoms, it  desposes of photon (with energy of order electron volts).

Due to radioactive decay over many millions of years, it is possible for the element uranium to decay in

Answers

The uranium within these items is radioactive and should be treated with care. Uranium's most stable isotope, uranium-238, has a half-life of about 4,468,000,000 years. It decays into thorium-234 through alpha decay or decays through spontaneous fission.

Which of the following is most clearly an example of a physical change?
A. A solid dissolves when added to a liquid
B. A solution color when something is added
C. Two liquids produce heat when mixed together
D. A gas is released when two solutions are combined

Answers

a physical change does not produce a new substance.change in state or phrase.(melting, freezing, vaporization,condensation, sublimation)are physical changes.example of physical changes include crushing a can, melting an ice cube, and breaking a bottle.a chemical Change makes a substance that wasn't there before.

Answer: Option (A) is the correct answer.

Explanation:

Physical change is defined as a change that does not bring any changes in the chemical properties of a substance.

For example, solubility, density, volume etc are all physical changes.

When sugar dissolves in water then it is a physical change.

Whereas color change may not necessarily shows a physical change because a chemical change can also lead to color change of a solution or substance.

For example, rusting of iron is a chemical reaction in which color change also occurs.

Hence, we can conclude that a solid dissolves when added to a liquid is most clearly an example of a physical change.

How many grams of lead ii sulfide is produced when 25.0 g lead ii acetate reacts with excess hydrogen sulfide

Answers

Answer: 18.42 grams of lead (II) sulfide will be produced in the given reaction:

Explanation: The reaction of lead (II) acetate and hydrogen sulfide follows:

[tex](CH_3COO)_2Pb+H_2S\rightarrow PbS+2CH_3COOH[/tex]

To calculate the moles, we use the formula:

[tex]Moles=\frac{\text{Given mass}}{\text{Molar mass}}[/tex]    ....(1)

Molar mass of lead (II) acetate = 325.29 g/mol

Given mass of lead (II) acetate = 25 g

Putting values in above equation, we get:

[tex]Moles=\frac{25g}{325.29g/mol}=0.0768moles[/tex]

We are given that hydrogen sulfide is present in excess, so limiting reagent is lead (II) acetate because it limits the formation of product.

By stoichiometry of the reaction,

1 moles of lead (II) acetate produces 1 mole of lead (II) sulfide

So, 0.0768 moles of lead (II) acetate will produce = [tex]\frac{1}{1}\times 0.0768[/tex] = 0.0768 moles of lead (II) sulfide.

Now, to calculate the mass of lead (II) sulfide, we use equation 1, we get:

Molar mass of lead (II) sulfide = 239.3 g/mol

[tex]0.0768mol=\frac{\text{Given mass}}{239.3g/mol}[/tex]

[tex]\text{Mass of lead (II) sulfide}=18.42g[/tex]

When 25.0 g of lead (II) acetate reacts with excess hydrogen sulfide, 18.37 grams of lead (II) sulfide are produced, based on stoichiometry and molar mass calculations.

To calculate the number of grams of lead (II) sulfide produced when 25.0 g of lead (II) acetate reacts with excess hydrogen sulfide, first, you need to write the balanced chemical equation for the reaction:

Pb(C₂H₃O₂)₂+ H2S ightarrow PbS + 2C₂H₄O₂

This indicates that one mole of lead (II) acetate produces one mole of lead (II) sulfide. Next, find the molar mass of lead (II) acetate and lead (II) sulfide:

Molar mass of Pb(C₂H₃O₂)₂ = 325.29 g/mol

Molar mass of PbS = 239.26 g/mol

Then, calculate the number of moles of lead (II) acetate:

25.0 g Pb(C₂H₃O₂)₂ times (1 mol / 325.29 g) = 0.0768 mol

Assuming complete reaction and that lead (II) acetate is the limiting reagent, the same number of moles of PbS will be formed. Finally, calculate the mass of PbS:

0.0768 mol PbS times (239.26 g/mol) = 18.37 g of PbS

Therefore, 18.37 grams of lead (II) sulfide are produced.

The percentage composition of oxygen in the compound Ca(ClO3)2 is approximately

Answers

assume you have 1 mole (or any other number, it doesn't matter). Mass = 206.98 g/mole. This is straight from the molar mass so that's why I like to use 1 mole  

From the chemical formula, 1 mole of Ca(ClO3)2 contains 6 moles of oxygen atoms.  

Mass of 6 moles of O atoms = 6 moles * 16 g/mole = 96 g  

mass % oxygen = 96 g / 206.98 g * 100 = 46.4%.  

You could also do it on a mole percent. 1 mole of Ca(ClO3)2 contains 9 moles of atoms.  

6 moles of these are oxygen atoms so the mole % = 6 moles / 9 moles * 100 = 66.7 mole %

If you mean percent by weight or percent by composition? Ca(ClO3)2 is 67% O by composition (number of atoms) and, as calculated by Ricki, 46% by weight.

The percentage composition of oxygen in the compound Ca(ClO₃)₂is approximately is 46.38%.

What is percent composition?

Percent composition is defined as a convenient way to record concentration of solution.It is a expression which relates one element to compound as,mass of element/mass of compound ×100.Percent compositions helps in determination of amount of an element which is present in the compound.

Percent composition of a compound or an element is usually in terms of grams of an element or a compound.

In the given example, molar mass of calcium chlorate is 206.98 g/mole and that oxygen present in it is 96 g/mol,substituting these values in above formula we have, 206.98/96×100=46.38 %

Thus, the percentage composition of oxygen in the compound Ca(ClO₃)₂is approximately is 46.38%.

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When uranium-238 is transformed into thorium-234, it is represented by a balanced equation. What is missing from the equation of U-238 undergoing radioactive decay?

Answers

The unstable atomic nucleus of Uranium-238 emits ionizing particles and loses energy in order to achieve a stable state. This process is called the Radioactive decay. This isotope undergoes Alpha decay by emitting Alpha rays. It has a decay energy of 4.267 MeV.

Final answer:

The decay of uranium-238 to thorium-234 is represented by a nuclear equation that must balance in terms of both mass numbers and atomic numbers, owing to conservation laws. The emission of an alpha particle during the decay of U-238 results in Th-234, with the mass number decreasing by 4 and the atomic number by 2.

Explanation:

When uranium-238 decays to form thorium-234, this is represented by a nuclear equation owing to the transformation occurring within an atomic nucleus. According to conservation of mass and atomic numbers, the nuclear equation must balance, both in terms of the mass numbers and the atomic numbers. Considering uranium has an atomic number of 92 (Z = 92) and a mass number of 238, when it loses 2 protons and 2 neutrons which occurs during the emission of an alpha particle (He), we are left with thorium-234 (Th).

The balanced nuclear equation for this decay process is:

^238_92U → ^4_2He + ^234_90Th

This shows the loss of an alpha particle from uranium-238 which results in thorium-234. The sum of the mass numbers and atomic numbers on the reactant side must equal the sum on the product side, hence confirming that the equation is correctly balanced. The loss of four nuclear particles (2 protons and 2 neutrons) is accounted for by the alpha particle, reducing the mass number by 4 from 238 to 234, and dropping the atomic number from 92 to 90 which identifies the new element as thorium. Furthermore, this decay sequence continues as thorium-234 decays via beta emission to form protactinium-234, which then decays to uranium-234.

If an object starts at rest and moves 16 m north along a straight line for two seconds what is its average velocity

Answers

The answer would be 8 m/s. To find the answer you divide distance by time which is 16 divided by 2.

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